You should be using an e-mail service provider that allows you to schedule your e-mails to be sent out at a later date so you don’t have to worry about being available to press send right when you want the message to go out. When scheduling your messages you want to try to catch people when they are likely to be checking their e-mail regularly (so the inbox isn’t already piled up), and when they are in a frame of mind that makes them more likely to read your message.
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